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81.
Quach Thi Thanh Van Le Thi Vien Tran Thi Hong Hanh Phan Thi Thanh Huong Nguyen The Cuong Nguyen Phuong Thao 《Natural product research》2020,34(9):1276-1281
AbstractUsing various chromatographic separations, three new acylated flavonoid glycosides, namely barringosides G–I (1–3), were isolated from the water-soluble extract of Barringtonia racemosa branches and leaves. The structure elucidation was performed by extensive analysis of the 1D and 2D NMR and HR-QTOF-MS data. Of the isolated compounds, barringoside I (3) showed moderate inhibitory effects on LPS-induced NO production in RAW264.7 cells with an IC50 of 52.48?±?1.04?µM. 相似文献
82.
Le Hoang Vien Le Thi Hanh Tran Thi Hong Thanh Nguyen Van Nam Nguyen Hoai 《Natural product research》2020,34(8):1061-1067
AbstractFrom the MeOH extract of the Vietnamese sea cucumber Holothuria edulis, eight triterpene glycosides (1–8), including one new compound namely holothurin A5 (1), were isolated by using various chromatographic separations. Their structures were established by spectroscopic experiments including 1D, 2D NMR and HR-ESI-MS. Holothurin A5 (1) has a hydroperoxy group at C-25. To the best of our knowledge, this is the first report of this group in triterpene saponins obtained from sea cucumbers to date. In addition, the in vitro cytotoxicity against five human cancer cell lines (HepG2, KB, LNCaP, MCF7 and SK-Mel2) of all isolated compounds was also evaluated using SRB assays. 相似文献
83.
We consider the exterior Neumann problem of the Laplacian with boundary condition on a prolate spheroid. We propose to use
spherical radial basis functions in the solution of the boundary integral equation arising from the Dirichlet–to–Neumann map.
Our approach is particularly suitable for handling of scattered data, e.g. satellite data. We also propose a preconditioning
technique based on domain decomposition method to deal with ill-conditioned matrices arising from the approximation problem. 相似文献
84.
85.
Tran Van Hung 《Journal of Radioanalytical and Nuclear Chemistry》2011,287(1):103-106
The neutron temperature is a characteristic parameter in irradiation channels of reactor. For nuclides which have resonances
in the thermal neutron energy range, their Westcott g-factors are different from unity. The values of g-factors and cross-sections
of (n, γ) reaction of these nuclides are temperature dependence. The standard energy for tabulation of thermal neutron cross-section
(σ0) is that of room temperature (293.59 K or 20.43 °C), corresponding to a neutron energy 0.0253 eV or to a neutron velocity
of 2200 m/s. However, in the irradiation channels of reactor, the temperature is not exact at 20.43 °C. Thus, the temperature
at the irradiation position must be known to convert σ0 to σ(T). A method for determination of the neutron temperature in irradiation channels of Dalat reactor is presented by fitting
the thermal neutron spectrum obtained from the calculation using MCNP code. 相似文献
86.
Synthesis of cation-exchanged laponite suspensions by laser ablation of microsized-metal particles in liquid 总被引:1,自引:0,他引:1
Laser ablation in the liquid technique has been used to synthesize cation-exchanged laponite suspensions. In summary, laser ablation of the microsize-metal powder (Co, Al, and Cu) dispersed in an aqueous solution containing deionized water laponite crystals was carried out using laser beam generated by a single-mode, Q-switched Nd-Yag laser operating at 532 nm with a pulse duration of 5.5 ns and 10 Hz repetition rate. Laser fluence was 0.265 J/cm2 for all tests. For all samples, the mass fraction of laponite was 1%. General observations of the prepared samples indicated that an aqueous suspension of 1 wt% laponite retained its free flowing liquid phase characteristics even after aging for several weeks. When bivalent cationic metals (Cu, Co, Al) were ablated in it for about 1 h, even with a small amount of the metal (0.025% and 0.050%) were generated, the suspension became highly viscous and behaved as a shear-thinning and thixotropic material. That is, the suspension gelled strongly when it was allowed to rest. The gels, however, could easily be reverted to a low viscosity liquid with simple shaking. Information from TEM and XRD analysis indicated that such a sol-gel transformation might be due to the charge exchange between the cationic species produced during the laser ablation and the sodium ions in the interlayers of the clay sheets. 相似文献
87.
S. M. Arakelian A. V. Osipov I. O. Skryabin Tran Dinh Phong Nguyen Tran Thuath 《Bulletin of the Russian Academy of Sciences: Physics》2017,81(12):1416-1419
The current-voltage relationships of deposited structures are measured for cluster structures consisting of nanoparticles of lead telluride. Variation in the value of the tunnel current is shown. Optimum conditions for the possible emergence of quantum-hopping conductivity due to carrier tunneling (the characteristic sizes of the nanoclusters and the distances between them) are determined. 相似文献
88.
Our research involves the development of new cationic materials for anion-based applications. We report the solvothermal synthesis and characterization of Pb(3)F(5)NO(3), a new layered lead fluoride material that, unlike the majority of layered and open-framework materials, is cationic in charge. The structure consists of polyhedral lead centers connected by doubly and triply bridging fluoride groups. We quantitatively exchanged the interlamellar nitrate groups of Pb(3)F(5)NO(3) for dichromate, under ambient aqueous conditions. Nuclear magnetic resonance and UV-vis spectroscopy show the reaction proceeds to 61.0% completion in several days. The material is also stable to 450 degrees C, which is vastly superior to organic resins that are still the standard for anion-exchange. The presence of extraframework anions also opens up other potentially unique anion-based properties, such as new catalytic reactions, anion intercalation, or growth of anionic clusters within the void spaces of the cationic material. 相似文献
89.
Tezuka Y Stampoulis P Banskota AH Awale S Tran KQ Saiki I Kadota S 《Chemical & pharmaceutical bulletin》2000,48(11):1711-1719
From the MeOH extract of the aerial part of Vietnamese Orthosiphon stamineus, five new isopimarane-type diterpenes [orthosiphols F-J (1-5)] and two new diterpenes [staminols A (6) and B (7)] with a novel carbon-framework, to which we proposed the name "staminane", and three new highly-oxygenated staminane-type diterpenes [staminolactones A (8) and B (9) and norstaminol A (10)1 were isolated. Moreover, staminolactone A (8) is 8,14-secostaminane-type and staminolactone B (9) is 13,14-secostaminane-type, while norstaminol A (10) is 14-norstaminen-type. Together with these new diterpenes, sixteen known compounds were also isolated and identified to be: 7,3',4'-tri-O-methylluteolin (11), eupatorin (12), sinensetin (13), 5-hydroxy-6,7,3',4'-tetramethoxyflavone (14), salvigenin (15), ladanein (16), tetramethylscutellarein (17), 6-hydroxy-5,7,4'-trimethoxyflavone (18), vomifoliol (19), aurantiamide acetate (20), rosmarinic acid (21), caffeic acid (22), oleanolic acid (23), ursolic acid (24), betulinic acid (25), and beta-sitosterol (26). All the isolated compounds were tested for their cytotoxicity towards highly liver metastatic murine colon 26-L5 carcinoma cells, and the new diterpenes, except for 4, and flavonoids (11, 12, 16, 18) showed cytotoxicity with an ED50 value between 10 and 90 microg/ml. 相似文献
90.
Streubel R Schiemann U Jones PG Tran Huy NH Mathey F 《Angewandte Chemie (International ed. in English)》2000,39(20):3686-3688